(1) (a) (b) (c) Identify the three main products resulting from the OH initiated oxidation of 2,2-dimethylbutane, (CH3)3CCH₂CH3, in polluted urban air and propose mechanisms for their formation. Calculate the lifetime of 2,2-dimethylbutane in the troposphere given the following information; = k(OH+2,2-dimethylbutane) - 2.6 x 10-¹2 cm³ molecules! [OH] (average) 1 10° molecule cm³ Briefly describe a suitable method for measurement of 2,2- dimethylbutane in air.

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.9PAE
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QUESTION ONE:
Answer all parts
(i)
e
(a)
(b)
Identify the three main products resulting from the OH initiated
oxidation of 2,2-dimethylbutane, (CH3)3CCH₂CH3, in polluted urban air
and propose mechanisms for their formation.
Calculate the lifetime of 2,2-dimethylbutane in the troposphere given the
following information:
k(OH+2,2-dimethylbutane) = 2.6 x 10-12 cm³ molecule¯¹ s¹
[OH] (average) 1x 10° molecule cm-³
(c) Briefly describe a suitable method for measurement of 2,2-
dimethylbutane in air.
Transcribed Image Text:QUESTION ONE: Answer all parts (i) e (a) (b) Identify the three main products resulting from the OH initiated oxidation of 2,2-dimethylbutane, (CH3)3CCH₂CH3, in polluted urban air and propose mechanisms for their formation. Calculate the lifetime of 2,2-dimethylbutane in the troposphere given the following information: k(OH+2,2-dimethylbutane) = 2.6 x 10-12 cm³ molecule¯¹ s¹ [OH] (average) 1x 10° molecule cm-³ (c) Briefly describe a suitable method for measurement of 2,2- dimethylbutane in air.
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