(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter20: Transition Metals And Coordination Chemistry

Section: Chapter Questions

Problem 6Q: Four different octahedral chromium coordination compounds exist that all have the same oxidation...

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Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?
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