For Questions 20-24 consider the following scenario: A 0.8390 g of an unknown sample containing chloride was dissolved in water and reacted with an excess of AgNO3 solution. The following data was collected from the gravimetric analysis: Mass of Unknown Sample = 0.8390 g Mass of Filter Paper and Precipitate = 3.2174 g Mass of Filter Paper =1.0230 g The Mass of the Precipitate = 2.1944 g The chemical formula of the precipitate ABCI (s) >

For Questions 20-24 consider the following scenario: A 0.8390 g of an unknown sample containing chloride was dissolved in water and reacted with an excess of AgNO3 solution. The following data was collected from the gravimetric analysis: Mass of Unknown Sample = 0.8390 g Mass of Filter Paper and Precipitate = 3.2174 g Mass of Filter Paper =1.0230 g The Mass of the Precipitate = 2.1944 g The chemical formula of the precipitate ABCI (s) >

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter10: Solutions

Section: Chapter Questions

Problem 65QAP: Twenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is...

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The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?
Twenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is added to 50.0 mL of 2.45 M barium chloride. (a) What is the expected precipitate? (b) How many grams of precipitate are obtained? (c) What is the chloride concentration after precipitation is complete?
Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?
In most of its ionic compounds, cobalt is either Co(II) or Co(III). One such compound, containing chloride ion and waters of hydration, was analyzed, and the following results were obtained. A 0.256-g sample of the compound was dissolved in water, and excess silver nitrate was added. The silver chloride was filtered, dried, and weighed, and it bad a mass of 0.308 g. A second sample of 0.416 g of the compound was dissolved in water, and an excess of sodium hydroxide was added. The hydroxide salt was filtered and heated in a flame, forming cobalt(III) oxide. The mass of cobalt(III) oxide formed was 0.145 g. a. What is the percent composition, by mass, of the compound? b. Assuming the compound contains one cobalt ion per formula unit, what is the formula? c. Write balanced equations for the three reactions described.
On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
What mass of solid AgBr is produced when 100.0 mL of 0.150 M AgNO3 is added to 20.0 mL of 1.00 M NaBr?
A certain grade of steel is made by dissolving 5.0 g of carbon and 1.5 g of nickel per 100. g of molten iron. What is the mass percent of each component in the finished steel?
According to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?
Iron (II) can be oxidized to iron (III) by dichromate ion, which is reduced to chromium (III) in acid solution. A 2.5000-g sample of iron ore is dissolved and the iron converted into iron(II). Exactly 19.17? ml. of 0.0100 M Na2Cr2O7 is required in the titration. What percentage of the ore sample was iron?
What mass of solid aluminum hydroxide can be produced when 50.0 mL of 0.200 M Al(NO3)3 is added to 200.0 mL of 0.100 M KOH?