Manfred Eigen, a German physical chemist working dur- ing the 1970s and 1980s, earned a Nobel Prize for devel- oping the "temperature-jump" method for studying kinetics of very rapid reactions in solution, such as proton transfer. Eigen and his co-workers found that the specific rate of proton transfer from a water molecule to an ammonia molecule in a dilute aqueous solution is k = 2 x 10° s-'. The equilibrium constant Kµ, for the reaction of ammonia with water is 1.8 x 10-8, What, if anything, can be deduced from this information about the rate of transfer of a proton from NH; to a hydroxide ion? Write equations for any reactions you mention, making it clear to which reaction(s) any quoted constant(s) apply.
Manfred Eigen, a German physical chemist working dur- ing the 1970s and 1980s, earned a Nobel Prize for devel- oping the "temperature-jump" method for studying kinetics of very rapid reactions in solution, such as proton transfer. Eigen and his co-workers found that the specific rate of proton transfer from a water molecule to an ammonia molecule in a dilute aqueous solution is k = 2 x 10° s-'. The equilibrium constant Kµ, for the reaction of ammonia with water is 1.8 x 10-8, What, if anything, can be deduced from this information about the rate of transfer of a proton from NH; to a hydroxide ion? Write equations for any reactions you mention, making it clear to which reaction(s) any quoted constant(s) apply.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 83QRT
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