The following reaction mechanism has been proposed for the gas-phase reaction of CHC13 and Cl₂: k₁ Cl2(g) = 2 Cl(g) Step 1 (fast equilibrium): k.1 Step 2 (slow): Cl(g) + CHCl3(g) k3 k₂ HCl(g) + CC13(g) Step 3 (fast): Cl(g) + CCl3(g) CCl4(g) A. Write the balanced chemical equation for the overall reaction. B. Identify the intermediate/s in the mechanism.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The following reaction mechanism has been proposed for the gas-phase reaction of CHCl3 and Cl₂:
k₁
Cl2(g) = 2 Cl(g)
Step 1 (fast equilibrium):
k.1
Step 2 (slow):
Step 3 (fast):
Cl(g) + CHCl3(g)
k3
Cl(g) + CCl3(g) →
k₂
HCl(g) + CC13(g)
CC14(g)
A.
Write the balanced chemical equation for the overall reaction.
B. Identify the intermediate/s in the mechanism.
Transcribed Image Text:The following reaction mechanism has been proposed for the gas-phase reaction of CHCl3 and Cl₂: k₁ Cl2(g) = 2 Cl(g) Step 1 (fast equilibrium): k.1 Step 2 (slow): Step 3 (fast): Cl(g) + CHCl3(g) k3 Cl(g) + CCl3(g) → k₂ HCl(g) + CC13(g) CC14(g) A. Write the balanced chemical equation for the overall reaction. B. Identify the intermediate/s in the mechanism.
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