(a)
To show: The preparation of aniline by aromatic nitration, followed by reduction.
Interpretation: The preparation of aniline by aromatic nitration, followed by reduction is to be shown.
Concept introduction: Aniline is an
(b)
To show: The preparation of
Interpretation: The preparation of
Concept introduction: Para-bromoaniline is an aromatic compound with the formula
(c)
To show: The preparation of
Interpretation: The preparation of
Concept introduction: Mata-bromoaniline is an aromatic compound with the formula
(d)
To show: The preparation of
Interpretation: The preparation of
Concept introduction:
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Organic Chemistry (9th Edition)
- What two amides are obtained from the reaction of acetyl chloride with an equivalent of ethylamine and an equivalent of propylamine? a. Why is only one amide obtained from the reaction of acetyl chloride with an equivalent of ethylamine and an equivalent of triethylamine?arrow_forwardChapter 1 (Carbonyl compounds I) Explain how the class I carbonyl compound reacts? What will be the product when ethylamine and propyl amine reacts with acetyl chloride? Why only one amide obtained after the reaction of acetyl chloride with a mixture of ethylamine and trimethylamine? Excess amine is required in the reaction of acetyl chloride with amine whereas excess alcohol is not required in the reaction of acetyl chloride and alcohol. Why? List the following ester in order of decreasing reactivities towards hydrolysis with reason: Methyl benzoate, p-nitro methyl benzoate and p-methoxy methyl benzoate The reaction of an ester with an amine is not as slow as the reaction of an ester with water or an alcohol. Explain with reason. Explain why the rate of aminolysis of an ester cannot be increased by H+, OH- or OR-. How can you activate the carboxylic acid? Is acid catalyzed hydrolysis of acetamide a reversible or an irreversible reaction. Explain. Chapter 2 (Carbonyl compounds II)…arrow_forwardArrange the compounds in order of decreasing basicity A. ethylamine B. 2-aminoethanol C. 3-amino-1-propanolarrow_forward
- Which of these statements is NOT true about the reaction of amines with a cyclic anhydride like phthalic anhydride? a. Dimethylamine will give a cyclic imide product. b. Aniline will give a cyclic imide product. c. Triethylamine will give a cyclic imide product. d. The reaction undergoes a nucleophilic acyl substitution mechanism.arrow_forwardShow how to synthesize the following amines from the indicated starting materials below. Each of the final products may require several sequential steps. Draw the structure for each of the steps and show the reagents required. Starting material Final product b) Benzene m-bromoaniline c) ethylbenzene p-ethylaniline + o-ethylaniline d) benzene p-bromoaniline + o-bromoanilinearrow_forwardAmines can be protected by different protecting groups as indicated below. Which of the following is stable to an acid or a base in water. А. В. С. D.arrow_forward
- Which amines cannot be prepared by a Gabriel synthesis? Explain your choices. NH2 NH2 NH2 а. b. C. d.arrow_forwardBasicity of Amines Table 9.6 Observations on the basicity of each test sample. Sample Observations +/- Test tube 1: NaOH Test tube 2: Ethylamine Test tube 3: Aniline Arrange the test samples in order of increasing basicity? Explain briefly. Ferric Chloride Test Table 9.7 Observations on the reaction of each test sample with ferric chloride. Sample Observations +/- Test tube 1: NaOH logy Environment Scienc Test tube Ethylamine Test tube 3: Aniline Based on the test result, what is the structural requirement for a substance to react with the ferric chloride?arrow_forwardAmines and Amides 5. Base Hydrolysis a. Acetamide b. Benzamide Questions and Problems Q6 You have unknowns that are a carboxylic acid, an ester, and an amine. Describe how you would distinguish among them. రెండం we can acid an amine. Carlouxylicacid S have Dt ester s naue Sightiy ncutra DH and amine S Waue basic DH that 15jmore thon 7 Based on the OH of the Soutions distinquish Carooxy lic ester and an value Less than neutra 144arrow_forward
- Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. p-bromoanilinearrow_forward1. What is the merchanism of synthesis of salicylamide? 2. Does the boiling temperature too high affect the performance synthesis of salicylamide? 3. Comparison of likelihood of an amide reaction between salicylic acids, methyl salicylate and ethyl salicylate?arrow_forward16.13 Name each of the following amines by one of the methods used in Exercises 16.7, 16.9, and 16.11: a. CH₁₂ CH-C-NH, C. NH, CH₁₂ b. CH,CH,-N-CH₂CH, d. Cl CH, NH CH,CHCH,CHCH,arrow_forward
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